What is the significance of the terms — ‘isolated gaseous atom’ and ‘ground state’ while defining the ionization enthalpy and electron gain enthalpy?
If an isolated gaseous atom is in its ground state, then less amount energy would be required to remove an electron from it. Therefore, for comparison purposes, ionization enthalpy and electron gain enthalpy must be determined for an 'isolated gaseous atom' and its 'ground state'.