What are heat capacities at constant volume and constant pressure? What is the relationship between them?
Heat capacity at constant volume (Cv): Heat supplied to a system to raise its temperature through 1°C keeping the volume of the system constant is called its heat capacity at constant volume (Cv). Heat capacity at constant pressure (Cp): Heat supplied to a system to raise its temperature through 1°C keeping the external pressure constant is called its heat capacity at constant pressure (Cp). Relationship between Cp and Cv: Cp – Cv = R.